Thursday, December 31, 2015

ISO 14001 : 2015 (ENVIRONMENTAL MANAGEMENT SYSTEM)

ISO 14001 : 2015 (ENVIRONMENTAL MANAGEMENT SYSTEM)
Bayu Nurwinanto




This international standard specifies the requirements for an environmental management system that an organization can use to enhance its environmental performance. This international standard is intended for use by an organization seeking to manage its environmental responsibilities in a systematic manner that contributes to the environmental pillar of sustainability.

This international standard helps an organization achieve the intended outcomes of its environmental management system, which provide value for the environment, the organization itself and interested parties. Consistent with the organization’s environmental policy, the intended outcomes of an environmental management system include.
  • Enhancement of environmental performance.
  • Fulfilment of compliance obligation.
  • Achievement of environmental objectives.
Key Elements ISO 14001:2015
1. Context of the organization
1.1 Understanding the organization and its context
The organization shall determine external and internal issues that affect its ability to achieve the intended outcomes of its environmental management system. Such issues shall include environmental conditions being affected by or capable of affecting the organization.
1.2 Understanding the need and expectation of interested parties.
The organization shall determine :
  • The interested parties that are relevant to the environmental management system.
  • The relevant needs and expectations (i.e requirements) of these interested parties.
  • Which of these needs and expectation become its compliance obligations.
1.3 Determining the scope of the environmental management system
When determining this scope, the organization shall consider :
  • The external and internal issues.
  • The compliance obligations.
  • Its organizational unit, function, and physical boundaries.
  • Its activities, products and services.
  • Its authority and ability to exercise control and influence.
Once the scope is defined, all activities, product and services of the organization within that scope need to be included in the environmental management system.
The scope shall be maintained as documented information and be available to interested parties.

2. Leadership
2.1 Leadership and commitment
Top management shall demonstrate leadership and commitment with respect to the environmental management system.
2.2. Environmental policy
Top management shall establish, implement and maintain an environmental policy that, within the defined scope of its environmental management system.
2.3 Organizational roles, responsibilities and authorities
Top management shall ensure that the responsibilities and authorities for relevant roles are assigned and communicated within the organization.

3. Planning
3.1 Action to address risks and opportunities
  • Environmental aspects.
  • Compliance obligations.
  • Planning action.
3.2 Environmental objectives and planning to achieve them
  • Environmental objectives.
  • Planning actions to achieve environmental objectives.
4. Support
4.1 Resources
The organization shall determine and provide the resources needed for the establishment, implementation, maintenance and continual improvement of the environmental management system.
4.2 Competence
Determine the necessary competence of person doing work under its control that affects its environmental performance and its ability to fulfill its compliance obligations.
4.3 Awareness
  • The environmental policy.
  • The significant environmental aspects and related actual or potential environmental impacts associated with their work.
4.4 Communication
  • Internal Communication
  • external Communication
4.5 Documented Information
  • Creating and updating documented information.
  • Control of documented information.
5. Operation 
5.1 Operation planning and control 
5.2 Emergency preparedness and response.

6. Performance Evaluation
6.1 Monitoring, measurement, analysis and evaluation.
  • Evaluation of compliance
6.2 internal audit
  • Internal audit programme.
  • Management review.


7.   Improvement
7,1 Nonconformity and corrective action.
7.2 Continual improvement
The organization shall continually improve the suitability, adequacy and effectiveness of the environmental management system to enhance environmental performance.

Wednesday, December 30, 2015

Key Elements ISO 9001:2015

KEY ELEMENTS ISO 9001:2015
Bayu Nurwinanto

1. Context of the organization
  • Understanding the organisation & its context.
  • Understanding the needs & expectations of interested parties.
  • Determining the scope of the quality management system.
  • The quality management System.
  • Process approach.
2. Leadership
  • Leadership & Commitment.
  • Quality Policy.
  • Organizational roles, responsibilities & authorities.
3. Planning
  • Action to address risks & Opportunities.
  • Quality objectives & planning to achieve them.
  • Planning of changes.
4. Support
  • Resources.
  • Competence.
  • Awareness.
  • Communication.
  • Documented information.
5. Operation
  • Operational planning & control.
  • Determination of market needs & Interactions with customers.
  • Operational planning process.
  • Control of external provision of goods & services.
  • Development of goods & services.
  • Production of goods & service.
  • Release of goods & services.
  • Nonconforming goods & services.
6. Performance evaluation
  • Monitoring, measurement analysis & evaluation.
  • Internal Audit.
  • Management Review.
7. Improvement
  • Nonconformity & corrective action.
  • Improvement.














Saturday, December 12, 2015

Process Safety Management

PROCESS SAFETY MANAGEMENT
Bayu Nurwinanto


Process Safety Information
Hazards of the chemicals Used in the process
Complete and accurate written information concerning process chemicals, process technology, and process equipment is essential to an effective process safety management program and to a process hazard analysis. The compiled information will be a necessary resource to a variety of users including the team performing the process hazard analysis as required by PSM (Process Safety Management) those developing the training program and the operating procedure; contractors whose employees will be working with the process; those conducting the planners and insurance and enforcement officials.

The information to be compiled about the chemicals, including process intermediate, needs to be comprehensive enough for an accurate assessment of the fire and explosion characteristics, reactivity hazards, the safety and health hazards to workers and the corrosion and erosion effect on the process equipment and monitoring tools. Current material safety data safety data sheet (MSDS) information can be used to help meet this requirement but must be supplemented with process chemistry information, including runaway reaction and over-pressure hazards, if applicable.

Technology of the process
Process technology information will be a part of the process safety information package and should include employer established criteria for maximum inventory levels for process chemicals; limits beyond which would be consequences or results of deviation that could occur if operating beyond the established process limit. Employers are encouraged to use diagrams that will help users understand the process.

A block flow diagram is used to show the major process equipment and interconnecting process flow lines and flow rates, steam composition, temperature and pressures when necessary for clarity. The block flow diagram is a simplified diagram.

Process flow diagram are more complex and show all main flow steams including valves to enhance the understanding of the process as well as pressure and temperatures on all feed and product lines within all major vessels and in and out of headers and heat exchangers and points of pressure and temperature control (see figure for sample process flow diagram). Also information on construction materials, pump capacities and pressure heads, compressor horsepower and vessel design pressure and temperature are shown when necessary for clarity. In addition, process flow diagrams usually show major components of control loops along with key utilities.
Equipment in the process
Piping and instrument diagrams (P&ID) may be the more appropriate type diagram to show some of the above details as well as display the information for the piping designer and engineering staff. The P&ID are to be used to describe the relationships between equipment and instrumentation as well as other relevant information that will enhance clarity. Computer software programs that do P&ID or other diagram useful to the information package may be used to help meet this requirement.

The information pertaining to process equipment design must be documented. In other words, what codes and standard were relied on to establish good engineering practice? These codes and standard are published by such organization as the ASME, API, ANSI, National Fire Protection Association, American Society for Testing and Materials, The National Board of Boiler and Pressure Vessel Inspectors, National Association of Corrosion Engineers, American Society of Exchange Manufacturers Association ad Model building Code groups.

For existing equipment designed and constructed many years ago in accordance with the codes and standards available at that time and no longer in general use today, the employer must document which code and standards were used and that the design and construction along with the testing, inspection and operation are still suitable for the intended use. Where the process technology requires a design that departs from the applicable codes and standards, the employer must document that the design and construction are suitable for the intended purpose.

Process Hazards Analysis
A process hazards analysis (PHA), or evaluation is one of the most important elements of the process safety management program. A PHA is an organized and systematic effort to identify and analyze the significance of potential hazards associated with the processing or handling of highly hazardous chemical. A PHA provides information that will assist employers and employee in making decisions for improving safety and reducing the consequences of unwanted or unplanned releases of hazardous chemicals.

A PHA analyzes potential causes and consequences of fires, explosions, releases of toxic or flammable chemicals and major spills of hazardous chemicals. The PHA focuses on equipment, instrumentation, utilities, human action (routine and non-routine) and external factors that might affect the process.

The selection of a PHA methodology or technique will be influenced by many factors including how much is known about the process. Is it a process that has been operated for a long period of time with little or no innovation and extensive experience has been generated with its use? Or, is it new process or one that has been changed frequently by the inclusion of innovation features? Also, the size and complexity of the process will influence the decision as to the appropriate PHA methodology to use. All PHA methodologies are subject to certain limitations. For example, the Checklist methodology works well when the process is very stable and no changes are made, but it is not as effective when the process has undergone extensive change. The checklist may miss the most recent changes and consequently they would not be evaluated. Another limitation to be considered concerns the assumptions made by the team or analyst. The PHA is dependent on good judgments and the assumptions made during the study need to be documented and understood by the team and reviewer and kept for a future PHA.

The ideal team will have an intimate knowledge of the standards codes, specifications and regulations applicable to the process being studied. The selected team members need to be compatible and the team leader needs to be able to manage the team and the PHA Study. The team needs to be able to work together while benefiting from the expertise of others on the team or outside the team to resolve issues and to forge a consensus on the findings of the study and recommendations.

The application of a PHA to a process may involve the use of different methodologies for various parts of the process. For example, a process involving a series of unit operation of varying sizes, complexities and ages may use different methodologies and team members for each operation. Then the conclusions can be integrated into one final study and evaluation.

Finally, when an employer has a large continuous process with several control rooms for different portions of the process, such as for a distillation tower and a blending operation, the employer may wish to do each segment separately and then integrate the final results.

Small business covered by the rule often will have processes that have less storage volume and less capacity and may be less complicated than processes at a large facility. Therefore, OSHA would anticipate that the less complex methodologies would be used to meet the process hazard analysis criteria in the standard. These process hazard analyses can be done in less time and with fewer people being involved. A less complex process generally means that less data, P&ID, and process information are needed to perform a process hazard analysis.

Operating Procedures
Operating procedures describe tasks to be performed, data to be recorded, operating condition to be maintained, sample to be collected and safety and health precautions to be taken. The procedures need to technically accurate, understandable to employees and revised periodically to ensure that reflect current operations. The process safety information package helps to ensure that the operating procedures and practices are consistent with the known hazards of the chemicals in the process and that the operating parameters are correct. Operating procedures should be reviewed by engineering staff and operating personnel to ensure their accuracy and that they provide practical instructions on how to actually carry out job duties safety. Also the employer must certify annually that the operating procedures are current and accurate.

Operating procedures provide specific instruction or details on what steps are to taken or followed in carrying out the stated procedures. The specific instructions should include the applicable safety precautions and appropriate information on safety implications. For example, the operating procedures addressing operating parameters will contain operating instruction about pressure limits, temperature ranges, flow rates, what to do when an upset condition occurs, and other subjects. Another example of using operating instructions to properly implement operating procedures is in stating up or shutting down the process. In these cases, different parameters will be required from those of normal operation. These operating instruction need to clearly indicate the appropriate allowances for heating up a unit to reach the normal operating parameters. Also the operating instructions need to describe the proper method for increasing the temperature of the unit until the normal operating temperatures are reached.

Computerized process control systems add complexity to operating instructions. These operating instructions need to describe the logic of the software as well as the relationship between the equipment and the control system; otherwise, it may not be apparent to the operator. Operating procedures and instructions are important for training operating personnel. The operating procedures are often viewed as the standard operating practices (SOP) for operations.

Contractor
Employers who use contractors to perform work in and around processes that involve highly hazardous chemicals have to establish a screening process so that they hire and use only contractors who accomplish the desired job tasks without compromising the safety and health of any employees at a facility. For contractors whose safety performance on the job is not known to the hiring employer, the employer must obtain information on injury and illness rates and experience and should obtain contractor references. In addition, the employer must ensure that the contractor has the appropriate job skill, knowledge and certifications (e.g., for pressure vessel welders). Contractor work methods and experience should be evaluated. For example, does the contractor conducting demolition work swing loads over operating processes or does the contractor avoid such hazards?

Maintaining a site injury and illness log for contractors is another method employers must use to track and maintain current knowledge of activities involving contract employees working on or adjacent to processes covered by PSM (Process Safety Management). Injury and illness logs of both the employer’s employees and contract employees allow the employer to have full knowledge of process injury and illness experience. This log contains information useful to those auditing process safety management compliance and those involved in incident investigations.

Pre-Startup Safety Review
For new processes, the employer will find a PHA helpful in improving the design and construction of the process from a reliability and quality point of view. The safe operation of the new process is enhanced by making use of the PHA recommendations before final installations are completed. P&ID should be completed, the operating procedures put in place, and the operating staff trained to run the process, before startup. The initial startup procedures and normal operating procedures must be fully evaluated as part of the pre-startup review to ensure a safe transfer into the normal operating mode.

For existing processes that have been shutdown for turnaround or modification, the employer must ensure that any changes other than “replacement in kind” made to the process during shutdown go through the management of change procedures. P&ID will need to be update, as necessary, as well as operating procedures and instructions. If the changes made to the process during shutdown are significant and affect the training program. The operating personnel as well as employees engaged in routine and non-routine work in the process area may need some refresher or additional training. Any incident investigation recommendations, compliance audits, or PHA recommendation need to be reviewed to see what affect they may have on the process before beginning the startup.

Mechanical Integrity of Equipment
Employers must review their maintenance programs and schedules to see if there are areas where “breakdown” maintenance is used rather than the more preferable on-going mechanical integrity program. Equipment used to process, store, or handle highly hazardous chemicals has to be designed, constructed, installed and maintained to minimize the risk of releases of such chemicals. This requires that a mechanical integrity program be in place to ensure the continued integrity of process equipment.

Elements of a mechanical integrity program include identifying and categorizing equipment and instrumentation, inspections and tests and their frequency: maintenance procedures; training of maintenance personnel; criteria for acceptable test results: and documentation of manufacturer recommendations for equipment and instrumentation.

Inspection and Testing
The mean time to failure of various instrumentation and equipment parts would be know from the manufacturer’s data or the employer’s experience with the parts, which the influence inspection and testing frequency and associated procedures. Also, applicable codes and standards such as the National Board Inspection Code, or those from the American Petroleum Institute, National Fire Protection Association, American National Standards Institute, American Society of Mechanical Engineers and other group provide information to help establish an effective testing and inspection frequency, as well as appropriate methodologies.

The applicable codes and standards provide criteria for external inspections for such items as foundation and supports, anchor bolts, concrete or steel support, guy wires, nozzles and sprinklers, pipe hangers, grounding connections, protective coatings and insulation, and external metal surface of piping and vessels. These codes and standards also provide information on methodologies for internal inspection and a frequency formula based on the corrosion rate of the materials of construction. Also, internal and external erosion must be considered along with corrosion effects for piping and valve. Where the corrosion rate is not known, a maximum inspection frequency is recommended (method of developing the corrosion rate are available in the codes). Internal inspections need to cover items such as the vessel shell, bottom and head; metallic linings; inspection for erosion, corrosion, cracking and bulges: internal equipment like trays, baffles, sensors and screens for erosion, corrosion of cracking and other deficiencies. Some of these Inspections may be performed by state or local government inspector under state and local statutes. However each employer must develop procedures to ensure that tests and inspection are conducted properly and that consistency is maintained even where different employees may be involved. Appropriate training must be provided to maintenance program procedures, safe practices and the proper use and application of special equipment or unique tools that may be required. This training is part of the overall training program called for in the standard.

Sunday, November 15, 2015

MOSITURE MEASUREMENT IN NATURAL GAS

MOSITURE MEASUREMENT IN NATURAL GAS
Bayu Nurwinanto

ABSTRACT
The measurement of moisture content in natural gas is extremely important, from a technical perspective and in order to ensure conformance to contractual specifications. Typically, this measurement is one of the most difficult to perform successfully - natural gas sources are generally dirty, corrosive, heavily moisture laden and at high pressure.  Moisture removal is a key stage of natural gas processing prior to sale and its efficiency is important in order to satisfy fiscal contractual obligations, to ensure that the gas is safe to transport and has the right properties for subsequent use.

This paper discusses the technology of natural gas processing and the demands it puts on the humidity measurement industry, both technically and commercially. This paper also describes the methods that may be employed to effect a measurement in natural gas and to ensure integrity and longevity.

Actual case histories are referred to within the paper as examples of good and bad practice.

INTRODUCTION
Natural gas extracted from underground sources is saturated with liquid water and heavier molecular weight hydrocarbon components. In order to meet the requirements for a clean, dry, wholly gaseous fuel suitable for transmission through pipelines and distribution for burning by end users, the gas must go through several stages of processing, including the removal of entrained liquids from the gas, followed by drying to reduce water vapour content.  The dehydration of natural gas is critical to the successful operation of the production facility and the whole distribution train through to the end user.  The presence of water vapour in concentrations above a few 10s of parts per million has potentially disastrous consequences.  The lifetime of a pipeline is governed by the rate at which corrosion occurs which is directly linked to the available moisture in the gas which promotes oxidation.  In addition, the formation of hydrates can reduce pipeline flow capacities, even leading to blockages, and potential damage to process filters, valves and compressors. Such hydrates are the combination of excessive water vapour with liquid hydrocarbons, which may condense out of the gas in the course of transmission, to form emulsions that, under process pressure conditions, are solid masses.  Furthermore, in the processing of gas prior to transmission, a cold temperature separator is most often used to extract the heavier molecular components to avoid the formation of such hydrocarbon liquid condensates at prevailing pipeline operating temperatures that change with climate.  The drying of natural gas to a dew point lower than the operating temperature of the chiller plant is of obvious importance to prevent freeze up problems, causing flow restriction, with resulting consequences in terms of plant operating efficiency.

For these reasons it is standard practice at natural gas production facilities, both on- and offshore, to measure the moisture content in natural gas on a continuous, on-line basis at critical points to ensure successful processing and efficient, reliable plant operation.  The successful design, installation and operation of industrial hygrometers for such applications requires special consideration to be given to the particular nature and composition of the gas being measured and the processing techniques being utilised.

Dehydration Process
The most common processing technique for drying natural gas is that of simple mechanical separator, to divide the gas from the liquids of the two phase flow coming from the gas field, followed by glycol dehydration.  Here a riser tower has an array of spray nozzles around it’s circumference through which glycol is injected, as a liquid desiccant, into the gas stream flowing up through the tower. The adsorption process results in moisture-laden glycol that coalesces into globules that are naturally forced, through flow dynamics, outward towards the wall of the tower.  The liquid glycol is collected in trays, piped out of the tower and is regenerated by heating to evaporate the absorbed moisture prior to re-injection in a continuous operating, re-circulating loop.  Such glycol contactors, as they are termed, are specified to achieve a moisture content of less than 3 Lb./MMSCF (pounds of moisture per million standard cubic feet of gas) under normal operating conditions.

The high flow velocity of gas through the contactor leads to possible carry through of glycol mist.  Consideration must be given to this characteristic if the application of a hygrometer is to be successful in monitoring the performance of the dehydration process.  Contamination of the moisture sensor or sample handling system results in a serious deadening in response for the analyser due to the moisture adsorption/desorption capacity of the glycol.  A conventional coalescing filter with fibre element positioned at the front end of the sampling system can effectively protect the moisture sensor from contamination but will not solve response problems unless any collected liquids are flushed out of the filter housing by a continuous flow from the drain port (Fig. 1). A membrane type filter offers the best protection in such glycol applications but is restricted to a maximum operating pressure of 10 MPa. These filters also work on a bypass flow arrangement but use a micro-porous membrane of fluorocarbon material to offer superior protection.
Figure 1. Schematic Diagram of a Typical Moisture Analyser
for Natural Gas Dehydration Plant
In addition to protection against liquid contamination, it is suggested by some suppliers of instrument sample filters for natural gas applications that an absorbent material, in the form of an in-line column of activated charcoal through which the sample flows, is used to remove glycol vapour.  In our experience the presence of glycol vapour, which has a low vapour pressure (130Pa at 53°C) and corresponding low maximum trace concentration, has little detrimental effect on the performance of sensing technologies like the Ceramic Moisture Sensor used for such measurements.

The measurement principle of such sensors is adsorption/desorption of water molecules into a hygroscopic layer between two conductive electrical plates - A substrate layer beneath and a porous top plate exposed to the flowing sample and through which moisture molecules freely permeate to maintain a natural equilibrium of moisture content. The variation of moisture adsorbed into the hygroscopic layer results in a corresponding change in the dielectric between the conductive plates and thus the ability to use this principle for continuous on-line measurement.   However, the Glycol molecule has similarities to that of water in that both have polar covalent bonds with an unequal sharing of electrons between a bond of oxygen and hydrogen atoms which, as a result, become negatively and positively charged respectively. 

As such both water and glycol molecules possess the potential to cause a response in the sensor if adsorbed into the hygroscopic layer as the oxygen atoms are attracted to the positively charged regions of the hygroscopic layer.  However, the maximum possible concentration of glycol vapour is extremely low relative to that of moisture which means that, given effective filtration to remove glycol mist as prescribed above, any effects to measurement accuracy are negligible.  However, the use of in-line adsorption cartridges, in addition to a filter, to remove such glycol vapour can have serious detrimental side effects. Activated charcoal is an effective desiccant with a capacity to adsorb moisture in addition to glycol vapour and as such will cause significant damping of the changes in moisture content of the analysis sample in response to process variations. If the process gas becomes drier, the activated charcoal will tend to act as a water source at the moisture analyser inlet and if the process gas gets wetter, the charcoal will desiccate it, giving a falsely dry reading.

Hydrocarbon dew point


For natural gas there are two dew-point temperatures of relevance, the water dew point, as we discuss here, and the hydrocarbon dewpoint.  The latter is quite simply the temperature at which liquid hydrocarbons condense out of the gas upon cooling.  Such liquid hydrocarbons comprise the heavier molecular weight components of the gas composition, typically butane and higher.  This parameter, as with water dew point, requires dedicated processing plant (in the form of condensing chillers) and purpose designed measurement instrumentation.  However, the significance to the measurement of water dew point arises if a moisture analyser using a condensing dew-point measurement technique is utilised such as a Bureau of Mines Apparatus1.  This form of manual visual cooled mirror dewpointmeter, and any other type of automated, condensing dew-point analyser, may give confusing results when used for water dew-point measurement in natural gas. This is because of the difficulty in observing the water dew point separately from that of hydrocarbons and glycol that are highly likely to condense on the mirror surface at a higher temperature than the water dew point (Fig. 2).  The use of a sensor based on a non-condensing measurement principle, such as the Ceramic Moisture Sensor, avoids this difficulty as it does not employ a condensation measurement technique and therefore will not suffer from such cross-measurement effects.
Figure 2. Hydrocarbon and Water Dew Point Variation with
Pressure 
for a Typical Natural Gas Composition

Conversion from measured dew point to moisture content

The pressure of natural gas is typically 4 to 8 MPa in processing plant and on-shore transmission whilst gas entering offshore pipelines is often compressed to 16 MPa or higher.  In any dew-point analysis the influence of gas pressure must be considered.  The Michell Ceramic Moisture Sensor as with its predecessors, the older aluminium oxide technologies, adsorb moisture in equilibrium with the gas sample flow to which it is exposed and thus exhibits a response to variations in water vapour pressure.  Water vapour pressure is directly related to dew point, which enables such sensors to be calibrated accurately and easily in the parameter of dew point.  The relationship between partial pressure of water vapour and dew point remains consistent irrespective of total gas pressure and the composition of the dry gas components.  Thus such a sensor calibrated by the instrument manufacturers on known dew point calibration gases, usually performed at atmospheric pressure, can be applied to accurately determine the dew point of any process gas at any chosen analysis pressure. The parameter of water dew point is the most widely used parameter to stipulate this element of gas quality in contractual supply specifications between gas producers and pipeline operators through to end customers.  However, in some specifications for process plant such as glycol dehydration contactors as well as pipeline operations it is more common for a maximum permissible moisture content to be stipulated.  The conversion from measured dew point to moisture content needs specific consideration to be given to the non-ideal behaviour of high-pressure natural gas that requires the use of enhancement factors when performing the conversion from measured dew point at known analysis pressure to moisture content. A number of sources of such conversion data, originating mainly from work carried out at IGT2, Chicago, in the 1950’s are in common usage today and are reproduced in a current ASTM standard3.  Data is only provided down to -40°C dew point, limiting its applicability in colder climate regions, where specifications for moisture content are stricter in order to avoid the potential for condensation to occur with the associated problems discussed earlier.  Furthermore, where desiccant columns are used as second stage dehydration plant, which is a necessity, fore instance, on a natural gas liquefaction plant to prevent freeze up inside the cryogenic process, then moisture levels need to be less than 1 ppmV, typically lower than 0.1 ppmV, which equates to less than -70°C dew point at process conditions.  Extrapolations of the IGT data have been used by Michell Instruments and other moisture analyser manufacturers but this introduces increased uncertainty of measurement and can lead to disputes at custody transfer between gas producers, pipeline operators and end customers if different conversion data is used.  Major European natural gas companies are now tending to use a new harmonised standard4 covering the full range of measurement.  The conclusion of this work, leading to a consistent approach amongst gas companies and instrumentation suppliers, has an added importance given the increased prevalence of inter-country pipelines. For applications requiring units of moisture content to be indicated then the conversion is usually performed in the measurement electronics of the hygrometer where the measured dew point, at a known pressure, is converted to the measurement unit desired by the natural gas company.  Units in regular use include Lb./MMSCFD (gas industry in USA and also world wide users of American designed processing plant) and mg/std.m³ (European specifications).  Knowing the pressure of analysis for the primary dew point measurement is critical to the accuracy of the unit conversion as a percentage error in defining the analysis pressure will directly transpose into the same percentage error in calculating the moisture content.  The analysir pressure should therefore either be fixed by a ‘peak shaving’ pressure regulator set to the minimum line pressure level or by on-line measurement of the analysis condition using a pressure transducer to provide a real time input of the variations with line pressure into the calculation (Fig. 1).

Sour natural gas
Further difficulty may also be experienced in interpreting water dewpoint measurements made in natural gas if a conversion to units of moisture content is required and if the gas composition contains a significant amount of carbon dioxide and/or hydrogen sulphide. Such ‘sour’ natural gas, as it is termed, is found in many gas fields in current production. The amount of moisture required to reach saturation water vapour pressure in H2S and CO2 is considerably higher than for moisture in methane or a ‘sweet’ natural gas composition at the same temperature.  As such the water dew point measured in a sour gas, irrespective of the measurement principle applied, will be significantly lower than for a sweet gas containing the same moisture content.  This needs to be compensated for, using published data5, and thus requires knowledge of the concentration of sour gas components. A typical example for a sour natural gas project can be taken from a major producer in Northern Germany.  Here a specification for maximum permissible moisture content is set at 50 mgH2O/std.m³ (equivalent to around -12°C dew point at line pressure of 7 MPa for sweet gas but lower than –20oC dew point for gas which is very sour).  This limit is set by safety standards to control the severe corrosion problems that are associated with sour gas and is enforced by The Bergamt, a German Federal authority.  For natural gas from such sour fields the concentration of H2S can be as high as 33% (mol) in extreme cases and 9 to 15%(mol) is average.  Sour natural gas production facilities include de-sulphurisation plant at an early stage in the processing with sulphur production being a major part of the operation.  Handling such gases prior to de-sulphurisation means careful consideration to the design of the processing plant and moisture analyser alike.  The obvious corrosion difficulties are compounded by the characteristic of H2S to promote sulphide stress cracking6 in metallic materials and the potentially fatal consequences of any leakage of sour gas as H2S, which cannot be detected by the human sense of smell above 200 ppm concentration, is highly toxic attacking the nervous system. The application of a moisture analyser for sour gas measurement requires a sensing technology that can perform satisfactorily in these most aggressive of gas media.  The Ceramic Moisture Sensor has been successfully used in these applications for some years.  The materials selected for the active device of this sensor are exclusively ceramics and base metals that are inert by nature and offer good resilience to chemical attack.  This combined with the robust design and careful selection of materials for the construction of the other gas-wetted parts of the sensor affords reliable service in this application.  Experience has been gained over the last five years with two types of installation method.  The first installation type is the conventional method used for a natural gas installation, that of remote sampling with a sample conditioning system (Fig. 1) but in such sour gas applications all sample wetted components must be selected strictly in accordance with NACE6 requirements, with significant cost implications.  In this case the sample flow exhausting from the system is taken to a flare where the toxic gas is rendered safe by burning.  The alternative installation type is direct insertion ‘in-line’ with the Ceramic Moisture Sensor being mounted at the tip of a specially adapted, stainless steel probe assembly that inserts directly into the process pipeline.  The advantages of this installation arrangement is that the sour gas remains in the pipeline, so removing the risks and costs associated with deploying a conventional sampling in such a sour gas application.  The speed of response for such an installation is extremely fast but a major disadvantage is the difficulty involved in removing the sensor probe assembly from the pipeline that is required for periodic maintenance of the sensor calibration.  This, as for all sour gas applications of the Ceramic Moisture Sensor, is recommended on a six monthly schedule, which, as these sensors are fully interchangeable, is achieved by exchange of the sensor in use for a freshly calibrated sensor carrying a detailed certification of calibration.  A further disadvantage is the lack of protection to glycol contamination that is afforded by such direct insertion.

Some Examples of Successful Applications
Glycol Dehydration – Underground Gas Storage Facility
Michell’s Ceramic Moisture Sensor has been implemented successfully to measure water dew point in high-pressure natural gas stored in large, natural underground storage caverns in mainland Europe. Storage pressures of up to 30 MPa mean that the gas must be very dry in order to prevent condensation occurring. Both water and hydrocarbon dew-point temperatures are measured during filling (pressurisation) and usage (de-pressurisation) cycles. The storage facility is used to meet demand in peak periods and may be non-active in the summer months. Therefore reliability is a vital factor, as the most likely time for a moisture analyser to fail is when there  is no gas flow and a corrosive, moist or contaminated, stale sample is presented to the sensor for an extended period of time.
Fiscal Metering at Gas Transfer Points – European Pipelines
Michell’s Cermet and Cermet II IS Hygrometer systems are used for the continuous measurement of the moisture content in natural gas that is transferred from one transmission company to another, normally across country borders. In one particular case, natural gas from a Russian source is measured after glycol dehydration at its transfer point into Germany, where the dew point must be lower than 0 oC at any line pressure, up to 10MPa.  Performance of the on-line Cermet II IS measurement system is validated by regular reference against a regularly-calibrated CERMAX IS portable hygrometer. At any such transfer point it is vital that the gas dew point is measured, particularly if there is to be mixing of gases from different sources. Whilst it is possible to calculate the resultant dew point from a volumetric mixture of two or more sources of gas, practical verification is required for contractual conformity.
Sour Gas Moisture Measurement
At a site in Germany, a special application has been successfully fulfilled, for measurement in sour natural gas. At this site the NH3 and H2S concentrations are as high as 33%, but the Michell Ceramic Moisture Sensor has been proven in practice to operate successfully over a number of years. Special materials of construction have been used to ensure that electrical contacts to the Moisture Sensor are not corroded by the high NH3 and H2S content, though the sensor active surface is of the standard Michell design. In the past, other analysers had a maximum operating life of only a few weeks and in some cases just hours or days. With the Michell Ceramic Moisture Sensor the calibration interval has been extended to six months.
LNG Production
Gas exporting countries have a need to verify the quality of natural gas prior to liquefaction, for bulk transportation by sea. Similarly, the importing gas company will need to verify the quality of the LNG as-delivered. Michell has successfully implemented its Ceramic Moisture Sensor technology on many LNG plants, particularly in the Middle East region, for measurement of sub-ppm moisture levels at relatively high line pressures. This application is reasonably simple, as the LNG has been processed to remove heavy hydrocarbons, most of the moisture and is usually very low in H2S and other corrosive components.
Low Pressure Measurements at Consumer Points
Often forgotten, the end-point for much natural gas is in the consumer chain at low pressure. Here, there is normally a specification that requires the dew point to be lower than –26 oC. Two factors are important. The first is to ensure that the calorific value of the end-user gas meets specification. Excess moisture will effectively reduce the CV and therefore must be kept to an acceptably low level. Second, the dew point must be low enough to ensure that no condensation (and therefore subsequent pipeline freezing and possible fracture) can occur in winter conditions. In some countries where winter temperatures dictate, the specification may be even more stringent. Michell’s CERMAX IS portable hygrometer is used to rapidly determine the moisture content in low-pressure consumer gas lines to determine contractual conformance and to help trace leaks. Michell has also supplied many gas authorities with humidity calibration equipment to enable local calibration of field instruments, maintaining a traceability chain back to UK, US and other national humidity standards.

CONCLUSION
The application of moisture analysers for the measurement of natural gas is not simple and straightforward.  There are many aspects to be considered that are unique to natural gas and that can greatly affect the reliability of both the instrument in service and of the measurement data that it provides.  Detailed consultation between instrument manufacturer and their customers in the natural gas industry is required to device the best solution to each individual application.